{2-(4-Hydroxyphenyl)-2-[(3-methoxy-2-oxidobenzylidene)amino-κ2 O 2,N]propanoato-κO}(1,10-phenanthroline-κ2 N,N′)copper(II) dihydrate
نویسندگان
چکیده
In the title complex, [Cu(C(17)H(15)NO(5))(C(12)H(8)N(2))]·2H(2)O, the central Cu(II) ion is five-coordinate, bound to one N atom and two O atoms from the Schiff base ligand and by two N atoms from a 1,10-phenanthroline ligand in a distorted square-pyramidal configuration. In the crystal, inter-molecular O-H⋯O and C-H⋯O hydrogen bonds form a two-dimensional network parallel to (001).
منابع مشابه
{2-[(5-Bromo-2-oxidobenzylidene)amino-κ2 N,O]-3-methylpentanoato-κO}(1,10-phenanthroline-κ2 N,N′)copper(II) dihydrate
In the title compound, [Cu(C(13)H(14)BrNO(3))(C(12)H(8)N(2))]·2H(2)O, the Cu(II) atom is penta-coordinated in a square-pyramidal geometry. The crystal packing is stabilized by O-H⋯O hydrogen bonds.
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In the title complex, [Cu(C(12)H(13)NO(5))(C(12)H(8)N(2))]·0.5H(2)O, the Cu(II) ion is five-coordinated by one N atom and two O atoms from a tridentate Schiff base ligand, derived from the condensation of l-threonine and o-vanillin, and two N atoms from a 1,10-phenanthroline ligand in a distorted square-pyramidal geometry. In the crystal, inter-molecular O-H⋯O hydrogen bonds form a one-dimensio...
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The asymmetric unit of the title complex, [Cu(C(14)H(17)NO(4))(C(12)H(8)N(2))]·H(2)O, contains two independent Cu(II) complex mol-ecules and two uncoordinated water mol-ecules. In each complex mol-ecule, the Cu atom is O,N,O'-chelated by the tridentate Schiff base ligand and N,N'-chelated by the 1,10-phenanthroline ligand in a distorted square-pyramidal geometry. The Cu-N bond distances in the ...
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متن کاملBis(μ2-2-chlorobenzoato-κ2 O:O′)bis[(2-chlorobenzoato-κO)(1,10-phenanthroline-κ2 N:N′)copper(II)] dihydrate
In the title compound, [Cu(2)(C(7)H(4)ClO(2))(4)(C(12)H(8)N(2))(2)]·2H(2)O, the two crystallographically independent dinuclear complex mol-ecules, A and B, have different Cu⋯Cu separations, viz. 3.286 (1) Å in A and 3.451 (1) Å in B. Both independent mol-ecules reside on inversion centres, so the asymmetric unit contains a half-mol-ecule each of A and B and two water mol-ecules. Each Cu atom ha...
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011